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Reducing dislocations in gallium arsenide on silicon templates

Ernesto J. Sager by Ernesto J. Sager
September 6, 2025
in Templates
0

University of California, Santa Barbara (UCSB) within the USA has been running to optimize gallium arsenide (GaAs) molecular beam epitaxy (MBE) on gallium phosphide on silicon (GaP/Si) [Daehwan Jung et al., J. Appl. Phys., vol122, p225703, 2017]. Normally, the increase of GaAs on Si uses off-axis substrates to avoid anti-section domains. On-axis silicon is favored for compatibility with CMOS processing foundries. The lattice mismatch between GaAs and Si is ~4%, mainly due to dislocations.

Reducing dislocations in gallium arsenide on silicon templates 1

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The researchers controlled to lessen threading dislocation densities (TDDs) to 7.2×106/cm2, a factor of 40 decrease from that of an unoptimized method. They comment: “We accept as true that those exceptional GaAs buffer layers with low TDDs and clean surfaces will serve as flexible templates for high-performance Si-based optoelectronic gadgets, including lasers and photodetectors as well as a myriad of photonic included circuits crafted from those gadgets.”

The researchers used an industrial 300mm GaP/Si (001) template from NAsPIII/V GmbH. The expected unintentional miscut of the template becomes doubtlessly most effective zero.1-zero- 2°. The silicon wafer was subjected to a special pre-epitaxial warmness treatment designed to terminate anti-section domain names in the 45nm GaP layer.

The wafer was split into small pieces and placed on molybdenum adapting plates within the Veeco MBE chamber. After oxide desorption, the increase commenced with 100nm GaAs at 550 hundred-550°C. The temperature was then raised to six hundred°C for a 3μm GaAs layer increase.

Electron channeling evaluation imaging (ECCI) measurements gave a threading dislocation density (TDD) of ~2.8×108/cm2 averaged over a 1800μm2 vicinity on a reference unoptimized GaAs/GaP/Si sample, which became constant with outcomes from extra traditional plan-view transmission electron microscopy (TEM). ECCI lets in dislocation density checks over large areas, decreasing uncertainties. Root-mean-rectangular (RMS) roughness of the reference became 7.8nm, keeping with atomic force microscopy (AFM) on 10μmx10μm fields.

Various optimizations were applied to the growth process: in-situ thermal cycle annealing, dislocation clear-out layers, and changing the increased temperature of the low-temperature GaAs layer.

The annealing consisted of 500°C low-temperature GaAs, 1.5μm high-temperature GaAs, 4x thermal cycling between 700 hundred°C and 320°C, and 1.5μm extra high-temperature GaAs. ECCI measurements gave a TDD of 5.5×107/cm2. RMS roughness was four.8nm. The team believes that the dislocations are eliminated by using gliding and misfit fusing, or annihilating.

A style of dislocation filter-out layers was tested. The first-class worried 10 durations of 10nm indium gallium arsenide (In0.1Ga0.9As) and 10nm GaAs carried out after thermal cycle annealing, giving 7.2×106/cm2 TDD and a couple of.9nm RMS roughness. The 200nm filter was capped with 1.3μm GaAs. The InGaAs turned into applied at 500°C. Somewhat decreased TDDs of 1.2-1.4×106/cm^2 have been accomplished with metal-natural chemical vapor deposition (MOCVD) on 4-6° offcut substrates. Also, better annealing temperatures may be reached in MOCVD chambers.

Reducing dislocations in gallium arsenide on silicon templates 2

What is the appeal of Time Travel as a style of writing? Is it the idea that we can go again and fix our lives? Or the enchantment of watching history spread? Maybe it is the idea that the whole thing takes place for a cause. Regardless of your “why,” you want an awesome “how” to make time tour a truth. Below are 5 examples of how you may make that appear. Don’t fear, none of them has anything to do with Albert Einstein’s Theory of Relativity.

1. Mechanical – Most Sci-Fi fanatics are acquainted with computerized time visiting. What do Dr. Who and Back to the Future have in common? They each have machines of a few kinds that permit characters to head ahead or go back in time. This is how the most common method writers use to get their topics from factor A to point B. The benefits are that you do not surely must explain the mechanics, count on it working, and stick to the tale. The drawback is ensuring you don’t sound like a Dr. Who or Back to the Future rip-off.

2. A Natural Phenomenon – Relying on a natural phenomenon is touch-specific. TV series like Star Trek and Stargate use these a lot. This consists of black holes, wormholes, and the ever-famous rip within the time’s material. In these tales, the time journey is not normally planned; this is thrust upon the characters. Advantages are that it’s usually excessively suspenseful and makes an amazing plot twist. The downside is that they may normally be more difficult to explain and regularly require area tours as some other places to research. Examples of this include A Wrinkle in Time and the display Sliders.

Three. Hypnosis or Meditation – If you operate hypnosis or meditation to travel in time, the character’s thoughts are doing all of the work. Think of Somewhere in Time or Time and Again. This makes the time journey confined to the best ones, those who have the strength of will. Advantages are that this puts your individuality at stake in their very own destiny. The disadvantages are that the individual should spend a lot of effort to hold that truth, and that any small detail can disrupt the adventure.

Reducing dislocations in gallium arsenide on silicon templates 3

Four. Sleep or Dreams – If you use sleep or dreams, this is a shape of time journey going on to your individual, but much less technical than a wormhole. Often used to teach someone a lesson. Think Rip Van Winkle or A Christmas Carol. Advantages are that it may be accepted with the aid of more people, including youngsters, as it does not sound like Sci-Fi. A disadvantage is that it can be difficult to make a dream, now, not sound cliché.

Five. Magic or Enchanted Items start to blur the road between Sci-Fi and Fantasy. The Story of the Amulet and Harry Potter and the Prisoner of Azkaban both use items that are not conventional time machines. Advantages are that you get to make up your guidelines because it is magic, despite everything. Disadvantages consist of not all sci-fi fanatics like delusion, and vice versa. This normally involves extra backstory, which you ought to paintings in (the history of the object, how the person came to own the item, and so on).

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Ernesto J. Sager

Ernesto J. Sager

Infuriatingly humble internet advocate. Unable to type with boxing gloves on. Alcohol expert. Twitter scholar. Creator. Spent 2001-2005 consulting about Virgin Mary figurines in Salisbury, MD. Spent 2002-2008 licensing corncob pipes in Phoenix, AZ. Spent 2002-2009 investing in glucose in Gainesville, FL. Spent 2002-2010 deploying Roombas in Suffolk, NY. Spent college summers testing the market for soap scum in the UK. Prior to my current job I was lecturing about birdhouses in Cuba.

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